Premium
Réactions de germylènes avec divers oxirannes et le thiiranne. Mise en évidence de germanones et germathiones intermédiaires. Communication préliminaire
Author(s) -
Barrau Jacques,
Bouchaut Marsan,
Lavayssiere Hélène,
Dousse Gabriel,
Satgé Jacques
Publication year - 1979
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19790620122
Subject(s) - chemistry , thiirane , medicinal chemistry , organic chemistry , ring (chemistry)
Complexed dialkylgermylenes R 2 GeNR 3 or R 2 GePy react with oxiranes or thiirane and lead to dialkylgermanone and germathione via germaoxetanes or germathiacyclobutane. The formation of germadioxolanes or germadithiolane finally observed arises from condensation of dialkylgermanone (or germathione) on oxiranes (or thiirane).