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Etude sur les composés organométalliques. XVIII . Synthèse et caractérisation du μ‐oxo‐bis (dicyclopentadiènylméthyltitane IV)
Author(s) -
Surer Hansruedi,
Claude Saturnin,
JacotGuillarmod André
Publication year - 1978
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19780610820
Subject(s) - chemistry , methyllithium , thermal decomposition , medicinal chemistry , autocatalysis , stereochemistry , organic chemistry , catalysis
Studies of Organometallic Compounds. XVII: Synthesis and Caracterisation of μ‐oxo‐bis(dicyclopentadienylmethyltitane IV) (Cp 2 TiCH 3 ) 2 O is obtained by reacting (Cp 2 TiCl) 2 O with methyllithium. IR., NMR. and MS. spectrum are reported. Autocatalytic decomposition of the product is inferred from differential thermal analytic measurements.