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Einfluss der Lipophilie von 3, 6‐Dioxakorksäurediamiden auf ihr Verhalten als Ionophore
Author(s) -
Bissig René,
Oesch Urs,
Pretsch Ernö,
Morf Werner E.,
Simon Wilhelm
Publication year - 1978
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19780610504
Subject(s) - chemistry , ionophore , lipophilicity , aqueous solution , phase (matter) , membrane , ion , stereochemistry , organic chemistry , biochemistry
Influence of the lipophilicity of 3,6‐dioxaoctanedioic diamides on their ion carrier properties A series of lipophilic 3,6‐dioxaoctanedioic diamides (potential ionophores for Ca 2+ ) have been prepared. With increasing lipophilicity the ionophoric behavior of these ligands vanishes. This loss is shown to be due to kinetic limitations in the exchange reactions between aqueous phase and membrane phase.