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Alkylaminopyridines and some Analogues as Derivatives for the structure elucidation of long aliphatic chains by mass spectrometry
Author(s) -
Vetter Walter,
Meister Walter,
Oesterhelt Gottfried
Publication year - 1978
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19780610411
Subject(s) - chemistry , mass spectrometry , alkylation , mass spectrum , chain (unit) , primary (astronomy) , double bond , side chain , stereochemistry , computational chemistry , organic chemistry , chromatography , polymer , physics , astronomy , catalysis
Several long chain primary alcohols (saturated, monoolefinic and methyl branched) have been converted via their mesylates into various long chain alkylated aromatic compounds with basic character, and their mass spectra compared. The spectra of 2‐alkylaminopyridines and to some extent those of 3‐alkylaminopyridines exhibit most clearly the structure of the aliphatic chain, allowing the localization of branchings and double bonds.