Photochemical Behaviour of 17β‐Acetoxy‐4‐aza‐1,5‐androstadien‐3‐one: Photo‐oxidation  vs.  Di‐π‐methane Rearrangement | Zendy

Vallet José Alberto | Zendy; Cánovas Antonio | Zendy; Boix José | Zendy; Bonet JuanJulio | Zendy

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Photochemical Behaviour of 17β‐Acetoxy‐4‐aza‐1,5‐androstadien‐3‐one: Photo‐oxidation vs. Di‐π‐methane Rearrangement

Author(s) -

Vallet José Alberto,

Cánovas Antonio,

Boix José,

Bonet JuanJulio

Publication year - 1978

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19780610331

Subject(s) - chemistry , moiety , photochemistry , irradiation , methane , photodissociation , stereochemistry , organic chemistry , physics , nuclear physics

The irradiation of the title compound 6 with UV. light and under photosensitized oxidation conditions yields products which are characteristic of the photo‐oxidation of the enamide moiety of 6 . In contrast to the situation encountered in the case of the irradiation of its carbocyclic and 4‐oxa analogues 1 and 2 , respectively, no compound resulting from a di‐π‐methane rearrangement of the Δ 1,5(6) ‐unsaturated system of 6 has been so far detected.

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