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Hexakis (methylidene)‐cyclohexane (“[6]Radialene”). Chemical and spectral properties
Author(s) -
Schiess Peter,
Heitzmann Markus
Publication year - 1978
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19780610232
Subject(s) - chemistry , mesitylene , cyclohexane , pyrolysis , chlorine , tris , molecule , spectral properties , photochemistry , flash (photography) , polymer chemistry , organic chemistry , benzene , computational chemistry , optics , biochemistry , physics
Upon flash pyrolysis between 580 to 660°, 2,4,6‐tris(chloromethyl)mesitylene ( 2 ) leads to products formed through the loss of one, two and three molecules of HCl. The highly reactive chlorine free product is shown to be [6]radialene ( 1 ) both by its chemical reactions and by its spectral properties.
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