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Biosynthèse de la farnésylacétone‐( E,E ) par les glandes androgènes du crabe carcinus maenas
Author(s) -
Férézou JeanPierre,
Barbier Michel,
BerreurBonnenfant Josette
Publication year - 1978
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19780610214
Subject(s) - carcinus maenas , chemistry , biosynthesis , biochemistry , crustacean , decapoda , biology , enzyme , zoology
Biosynthesis of E , E ‐farnesylacetone by the andogenic glands of the crab Carcinus maenas Using sodium acetate‐1,2‐[ 14 C] or mevalonic acid‐2‐[ 14 C], the biosynthesis of (E,E)‐farnesylacetone 1 by the androgenic glands of the crab Carcinus maenas, kept as organ subculture is demonstrated. Ozonolysis of the NaBH 4 reduction product 3 leads to three fragments the radioactivity of which has been measured after isolation by GC. It is thus established that the biosynthesis of 1 proceeds through geranylgeraniol. The hexahydroderivative 2 is not labelled in the two experiments.