Transition metal complexes with bidentate ligands spanning  trans ‐positions. VI . The preparation of some diaryl‐ and dialkyl derivatives of 2,11‐bis (phosphinomethyl)benzo [ c ]phenanthrene | Zendy

Kapoor Pramesh N. | Zendy; Venanzi Luigi M. | Zendy

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Transition metal complexes with bidentate ligands spanning trans ‐positions. VI . The preparation of some diaryl‐ and dialkyl derivatives of 2,11‐bis (phosphinomethyl)benzo [ c ]phenanthrene

Author(s) -

Kapoor Pramesh N.,

Venanzi Luigi M.

Publication year - 1977

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19770600835

Subject(s) - phenanthrene , chemistry , denticity , transition metal , medicinal chemistry , stereochemistry , metal , organic chemistry , catalysis

The preparation of the ditertiary phosphines 2,11‐bis (di‐ m ‐tolylphosphinomethyl)benzo [ c ]phenanthrene ( 1b ), 2,11‐bis (di‐ p ‐anisylphosphinomethyl)benzo‐[ c ]phenanthrene ( 1c ), 2,11‐bis (di‐ m ‐trifluoromethylphenylphosphinomethyl) benzo‐[ c ]phenanthrene ( 1d ), 2,11‐bis (dicyclohexylphosphinomethyl)benzo [ c ]phenanthrene ( 1e ) and 2,11‐bis [di‐( t ‐butyl)phosphinomethyl]benzo [ c ]phenanthrene ( 1f ), by a combination of synthetic routes is described.

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