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Synthesis and structure of fluorotricyanomethane
Author(s) -
Britton Doyle,
Farooq Saleem,
Keese Reinhart
Publication year - 1977
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19770600430
Subject(s) - chemistry , orthorhombic crystal system , crystal structure , potassium , crystallography , group (periodic table) , stereochemistry , organic chemistry
Fluorotricyanomethane is prepared from potassium tricyanomethanide and perchlorylfluoride. The crystal structure of this compound (orthorhombic, space group P 2 1 2 1 2 1 , with a =6.270, b =6.734, c =11.776 Å) has been determined by X‐ray analysis. The results are discussed in relation to those of (NC) 3 CX (X=CH 3 , Cl, Br or CN).