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Metal ion exchange in square planar Nickel and Palladium Mercaptoethylamine Complexes
Author(s) -
Reichert R.,
Schläpfer C. W.
Publication year - 1977
Publication title -
helvetica chimica acta
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19770600305
Subject(s) - chemistry , palladium , nickel , metal , polymer chemistry , nuclear chemistry , planar , metal ions in aqueous solution , inorganic chemistry , organic chemistry , catalysis , computer graphics (images) , computer science
Austauschversuche mit radioaktivem Nickel zeigen, dass Ni 2+ und Pd 2+ in Mercaptoäthylamin(MEA‐)‐Komplexen austauschbar sind. Aus UV./VIS.‐ und 1 H‐NMR.‐spektroskopischen Daten geht hervor, dass die Anordnung der Metallionen in Ni 2 Pd(MEA) 4 Cl 2 symmetrisch ist (Ni Pd Ni), in NiPd 2 (MEA) 4 Cl 2 dagegen asymmetrisch (Ni Pd Pd).

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