Comportement an  1 H‐RMN. des diaryl‐1,3‐triazènes dans les solvants neutres et acides. III | Zendy

Vernin Gaston | Zendy; Siv Chhan | Zendy; Metzger Jacques | Zendy; Elguero José | Zendy; Archavlis André | Zendy

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Comportement an 1 H‐RMN. des diaryl‐1,3‐triazènes dans les solvants neutres et acides. III

Author(s) -

Vernin Gaston,

Siv Chhan,

Metzger Jacques,

Elguero José,

Archavlis André

Publication year - 1977

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19770600221

Subject(s) - chemistry , smiles rearrangement , proton nmr , decomposition , nuclear magnetic resonance spectroscopy , polymer chemistry , medicinal chemistry , stereochemistry , organic chemistry

1 H‐NMR. behaviour of 1,3‐diaryltriazenes in neutral and acidic solvents Formation and decomposition of 1,3‐di‐aryltriazenes can be studied by 1 H‐NMR. Triazenes decompose in acidic medium or by addition of isoamylnitrite: in the last case, the spectrum shows emission lines characteristic of the CINDP effect. At −80° the prototropic rate is slow enough to permit the observation of two aromatic systems.

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