Acetoxytropyliumbromid: Synthese, Strukturbeweis, Verhalten in Lösung | Zendy

Engel Peter | Zendy; Keller Urs Martin | Zendy; Bigler Peter | Zendy; Neuenschwander Markus | Zendy

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Acetoxytropyliumbromid: Synthese, Strukturbeweis, Verhalten in Lösung

Author(s) -

Engel Peter,

Keller Urs Martin,

Bigler Peter,

Neuenschwander Markus

Publication year - 1976

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19760590707

Subject(s) - chemistry , tropone , polar , salt (chemistry) , polymer chemistry , stereochemistry , medicinal chemistry , crystallography , physics , astronomy

Acetoxytropyliumbromide: Synthesis, Structural Evidence, Behaviour in Solution. Acetoxytropyliumbromide ( 9 ) is formed from tropone and acetylbromide. In solution the tropylium salt equilibrates with the educts, 9 being favored at low temperature in polar aprotic solvents. The structure of the title compound has been proved by X‐ray analysis, as well as by investigation of the 1 H‐NMR. spectra of solutions of 9 .

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