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Stereospezifische Synthese zweier 9, 11, 12, 13, 13a, 14‐Hexahydrodibenzo[ f, h ]pyrrolo[1, 2‐ b ]isochinoline
Author(s) -
Faber Ludwig,
Wiegrebe Wolfgang
Publication year - 1976
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19760590633
Subject(s) - chemistry , stereospecificity , isoquinoline , stereochemistry , organic chemistry , catalysis
Stereospecific Synthesis of two 9,11,12,13,13a,14‐hexahydrodibenzo[ f,h ]pyrrolo‐[1,2‐ b ]isoquinolines. The stereospecific synthesis of (13a S )‐(+)‐2,3,6‐ and 3,4,6‐trimethoxy‐9,11,12,13,13a,14‐hexahydrodibenzo[ f,h ]pyrrolo[1,2‐ b ]isoquinoline is described. The 2,3,6‐trimethoxy‐compound proved to be the optical antipode of (−)‐antofine, isolated from Cynanchum vincetoxicum L . Pers.
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