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Komplexone XLVII. The Stability of Palladium(II) Complexes with Aminopolycarboxylate Anions
Author(s) -
Anderegg Giorgio,
Malik Subhash C.
Publication year - 1976
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19760590511
Subject(s) - chemistry , palladium , thiocyanate , divalent , bromide , ionic bonding , stability constants of complexes , ion , ionic strength , inorganic chemistry , metal , divalent metal , metal ions in aqueous solution , medicinal chemistry , organic chemistry , catalysis , aqueous solution
The formation of Pd(II) complexes with aminopolycarboxylate anions has been investigated using pH and UV.‐spectrophotometric measurements at ionic strength 1 M and 20°. In some cases bromide or thiocyanate ions have been used as auxiliary ligands. Pd 2+ forms the strongest complexes of the hitherto investigated divalent metal ions. The stability constants are discussed in relation to the particular stereochemistry of Pd(II) complexes.