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The Aldehyde Ketone Rearrangement. Rearrangement of Bis(4‐methoxyphenyl)‐acetaldehyde into 4,4′‐Dimethoxydeoxybenzoin
Author(s) -
Tadros Wadie,
Tadros Raouf Ramzi,
Awad Sami Bassili
Publication year - 1976
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19760590202
Subject(s) - chemistry , acetaldehyde , aldehyde , ketone , carbonyl group , carroll rearrangement , rearrangement reaction , sulfuric acid , medicinal chemistry , stereochemistry , sigmatropic reaction , organic chemistry , ethanol , catalysis
The formyl carbonyl group in bis(4‐methoxyphenyl)‐acetaldehyde does not contribute to the formation of the carbonyl group in 4,4′‐dimethoxydeoxybenzoin when the former rearranges to the latter by treatment with 50% ( w / w ) sulfuric acid.
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