Piperaceae Alkaloids: Part III. Synthesis of N‐isobutyl‐11‐(3,4‐methylenedioxyphenyl)‐undeca‐2,4,6‐ trans, trans, trans ‐trienoic amide and N‐isobutyl‐11‐(3,4‐methylenedioxyphenyl)‐undeca‐2,8,10‐ trans, trans, trans ‐trienoic amide (piperstachine) | Zendy

Viswanathan Narayanan | Zendy; Balakrishnan Venkatachalam | Zendy; Joshi Balawant S. | Zendy; von Philipsborn Wolfgang | Zendy

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Piperaceae Alkaloids: Part III. Synthesis of N‐isobutyl‐11‐(3,4‐methylenedioxyphenyl)‐undeca‐2,4,6‐ trans, trans, trans ‐trienoic amide and N‐isobutyl‐11‐(3,4‐methylenedioxyphenyl)‐undeca‐2,8,10‐ trans, trans, trans ‐trienoic amide (piperstachine)

Author(s) -

Viswanathan Narayanan,

Balakrishnan Venkatachalam,

Joshi Balawant S.,

von Philipsborn Wolfgang

Publication year - 1975

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19750580717

Subject(s) - chemistry , amide , stereochemistry , cis–trans isomerism , organic chemistry

N‐Isobutyl‐11‐(3, 4‐methylenedioxyphenyl)‐undeca‐2,4,6‐ trans, trans, trans ‐trienoic amide (II) and N‐isobutyl‐11‐(3,4‐methylenedioxyphenyl)‐undeca‐2,8,10‐ trans, trans, trans ‐trienoic amide (III), two of the three possible structures of the alkaloid piperstachine, have been synthesized. Compound (III) has been found to be identical with piperstachine. The 1 H‐ and 13 C‐NMR. spectra of the compound (II) are discussed.

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