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Die stereospezifische Reduktion von (1 R )‐3‐ endo ‐Aminocampher zu (1 R )‐3‐ endo ‐Aminoborneol
Author(s) -
Pauling Horst
Publication year - 1975
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19750580631
Subject(s) - chemistry , stereospecificity , stereochemistry , ketone , medicinal chemistry , catalysis , organic chemistry
The highly stereospecific reduction of (1 R )‐3‐ endo ‐aminobornan‐2‐one ( 2 ) to [1 R ]‐3‐ endo ‐amino‐2‐ endom ‐bornanol ( 1 ) is described. This reaction is achieved by using alkylaluminumdichlorides, a new group of reducing agents for the reduction of the ketone 2 to the secondary alcohol 1 Diesc Reduktion ist Gegenstand van Patcntanmeldungen, z. B. [l].