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Ionisation Energies and the Electronic Structures of the N‐oxides of diazabenzenes
Author(s) -
Maier John P.,
Muller JeanFrançois,
Kubota Tanekazu
Publication year - 1975
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19750580618
Subject(s) - chemistry , x ray photoelectron spectroscopy , valence (chemistry) , spectral line , ionization , electronic structure , ionization energy , absorption spectroscopy , atomic physics , photoemission spectroscopy , analytical chemistry (journal) , computational chemistry , ion , nuclear magnetic resonance , organic chemistry , optics , physics , astronomy
The ionisation energies and the HeI photoelectron spectra of the N‐oxides of diazabenzenes are presented. The valence electronic structures of the N‐oxides are discussed in view of the ionisation energies, and the profiles, of the bands. The interpreted data are compared to calculations which are in good agreement. The results are correlated to the physicochemical studies, and particularly to the electronic absorption spectroscopy, of the N‐oxides. The assignment of the photoelectron spectra of the azabenzenes are considered with reference to the spectra of their N‐oxides.