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Studies of Organometallic Compounds XVI. The Crystal Structure of Di‐μ‐ethoxy‐bis(dibenzylethoxy‐titanium(IV))
Author(s) -
StoeckliEvans Helen
Publication year - 1975
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19750580206
Subject(s) - chemistry , monoclinic crystal system , trigonal bipyramidal molecular geometry , crystallography , dimer , alkoxy group , titanium , crystal structure , molecule , bipyramid , group (periodic table) , crystal (programming language) , oxygen atom , atom (system on chip) , stereochemistry , organic chemistry , alkyl , computer science , programming language , embedded system
The crystal structure of di‐μ‐ethoxy‐bis(dibenzylethoxy‐titanium(IV)), [(EtO) 2 Ti‐(CH 2 Ph) 2 ] 2 , has been determined from analysis of photographic X‐ray data. The crystal system is monoclinic, a = 7.93(2), b = 15.99(2), c = 13.40(2) Å, β = 92.7(3)°, space group P2 1 / c . The molecule is a dimer situated about a crystallographic center of symmetry. The two Ti atoms are joined by oxygen bridges. Each Ti atom is penta‐coordinated in the form of a distorted trigonal bipyramid.