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Terpenoids Derived from Linalyl Oxide. Part 1. The stereochemistry of the davanones
Author(s) -
Thomas Alan F.,
Thommen Walter,
Willhalm Bruno,
Hagaman Edward W.,
Wenkert Ernest
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570716
Subject(s) - chemistry , deuterium , oxide , solvent , stereochemistry , terpenoid , organic chemistry , terpene , physics , quantum mechanics
Natural (+)‐davanone is 6 S ,7 S ,10 R ‐2,6,10‐trimethyl‐7,10‐oxidododeca‐2,11‐dien‐5‐one ( 1 ). Equilibration of davanone with base leads to the four possible isomers, but only a single deuterium atom is exchanged when deuterium oxide is the solvent.
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