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Comparison of 13 C‐ and 1 H‐Magnetic Resonance Spectroscopy as Techniques for the Quantitative Investigation of Dynamic Processes. The cope rearrangement in bullvalene
Author(s) -
Oth Jean F. M.,
Müllen Klaus,
Gilles JeanMarie,
Schröder Gerhard
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570518
Subject(s) - chemistry , spins , spectroscopy , nuclear magnetic resonance spectroscopy , nuclear magnetic resonance , analytical chemistry (journal) , fourier transform , atomic physics , stereochemistry , condensed matter physics , physics , quantum mechanics , organic chemistry
The potential advantages of 13 C‐( 1 H‐noise decoupled) spectroscopy (in the Fourier transform mode) over 1 H‐spectroscopy for the quantitative investigation of molecular dynamic process is discussed. The Cope rearrangement in bullvalene, an example of complex exchange of spins over different magnetic sites, has been studied by both kinds of spectroscopy as a test.