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A Stereospecific Synthesis of ( E, Z )‐α, β‐γ, δ‐Diunsaturated Aldehydes, Ketones, and Esters Using the Benary Reaction
Author(s) -
Näf Ferdinand,
Decorzant René
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570507
Subject(s) - stereospecificity , chemistry , stereochemistry , medicinal chemistry , organic chemistry , catalysis
The reaction between ( Z )‐1‐alkenyllithium and ( E )‐β‐(N, N‐dialkylamino)‐α, β‐alkenals, ( E )‐β‐(N, N‐dialkylamino)‐α, β‐alkenones or ( E )‐β‐(N, N‐dialkylamino)‐α, β‐alkenoic esters yields mainly ( E, Z )‐α, β‐γ, δ‐diunsaturated aldehydes, ketones, or esters and is therefore highly stereospecific.