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Oxydation ausgewählter δ,ϵ‐ und ϵ,ξ‐ungesättigter Alkohole mit Blei(IV)‐acetat
Author(s) -
Zink Markus Peter,
Ehrenfreund Josef,
Wolf Hans Richard
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570419
Subject(s) - chemistry , bicyclic molecule , yield (engineering) , ether , medicinal chemistry , organic chemistry , materials science , metallurgy
The lead tetraacetate (LTA) oxidation of dihydro‐γ‐jonol ( 2 ) gives the new bicyclic ether 4 in high yield. On the other hand, LTA oxidation of the alcohols 8, 14, 20 , results in the formation of complex mixtures of oxidation products, from which the spiro compounds 10, 16, 22 , the bicyclic ethers 11, 12, 17, 18, 23 , and the carbonyl compounds 13, 19 have been isolated.