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Darstellung und Eigenschaften von π‐Cyclopentadienylrhodium‐bis(tert.‐phosphit)‐Komplexen
Author(s) -
Neukomm Heinrich,
Werner Helmut
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570414
Subject(s) - chemistry , mass spectrum , medicinal chemistry , stereochemistry , mass spectrometry , chromatography
The half‐sandwich type compounds C 5 H 5 Rh[P(OR) 3 ] 2 (R = CH 3 , C 2 H 5 , C 6 H 5 , p ‐CH 3 C 6 H 4 , p ‐ClC 6 H 4 ) have been prepared from [(P(OR) 3 ) 2 RhCl] 2 and NaC 5 H 5 . The NMR. data as well as the IR. and mass spectra of the new compounds will be discussed. The preparation of C 5 H 5 Rh(CO)P(OC 2 H 5 ) 3 is also reported.
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