8‐Oxabicyclo[5.1.0]octa‐2,4‐dien, reduktive und säurekatalysierte Ringöffnung | Zendy

Schiess Peter | Zendy; Wisson Markus | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

8‐Oxabicyclo[5.1.0]octa‐2,4‐dien, reduktive und säurekatalysierte Ringöffnung

Author(s) -

Schiess Peter,

Wisson Markus

Publication year - 1974

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19740570403

Subject(s) - chemistry , allylic rearrangement , cycloheptatriene , peracetic acid , medicinal chemistry , isomerization , ring (chemistry) , catalytic hydrogenation , hydrolysis , double bond , catalysis , stereochemistry , organic chemistry , hydrogen peroxide

8‐Oxabicyclo[5.1.0]octa‐2,4‐diene ( 1 ) is obtained from cycloheptatriene with commercial 40% peracetic acid. Upon catalytic and LiAlH 4 reduction the allylic CO‐bond in 1 is cleaved. Acid catalised hydrolysis leads to a mixture of all six possible isomeric cycloheptadienediols. With BF 3 in the absence of water isomerization to 3,5‐cycloptadienone is observed.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research