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Model Calculations on the Squalene Cyclization
Author(s) -
Gleiter Rolf,
Müllen Klaus
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570336
Subject(s) - chemistry , squalene , cndo/2 , double bond , stereochemistry , computational chemistry , methyl group , group (periodic table) , organic chemistry , molecule
As a model for the squalene cyclization the interaction between a methyl cation or a methyl radical and two double bonds has been studied using the CNDO/2 and INDO method. In both cases bond formation between the CH 3 ‐group and one double bond is facilitated by a second one, but not in a concerted way.
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