Premium
Nachbargruppeneffekte bei der massenspektrometrischen Fragmentierung: N‐Acetyl‐ω‐Phenylalkylamine . 20. Mitteilung über das massenspektrometrische verhalten von stickstoffverbindung
Author(s) -
Wild René,
Hesse Manfred
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570219
Subject(s) - chemistry , fragmentation (computing) , mass spectrum , medicinal chemistry , stereochemistry , deuterium , ion , organic chemistry , physics , quantum mechanics , computer science , operating system
The mass spectral behaviour of the difunctional alkane N‐acetyl‐4‐phenyl‐butylamine ( 3 ) was investigated. The main fragmentation of compound 3 is caused by the interaction on the two functional groups, which could be shown by comparison of the corresponding monofunctional compounds n ‐butylbenzene ( 4 ) and N‐acetyl‐ n ‐butylamine ( 5 ). On the bases of high resolution data, the analyses of metastable transitions and the comparison of the spectra of some homologs and deuterated analogs of 3 the structures and their genesis of the main fragment i ons were deducted.