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Metall‐π‐Komplexe des 2, 5‐Diphenyl‐1‐silacyclopentadiens
Author(s) -
Fink Walter
Publication year - 1974
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19740570116
Subject(s) - chemistry , cyclopentadienyl complex , metal , mass spectrum , medicinal chemistry , spectral properties , polymer chemistry , computational chemistry , organic chemistry , catalysis , ion
The preparation of 2.5‐diphenyl‐1‐silacyclopentadienes and their reaction with iron carbonyls and π‐cyclopentadienyl‐dicarbonylcobalt yielding metal‐π‐silole complexes is described. Mass spectral data indicate the existence of an ‘aromatic’ silacyclopentadienyl species.