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The Mode of Incorporation of Farnesyl Pyrophosphate into Verrucarol. Preliminary communication
Author(s) -
Arigoni Duilio,
Cane David E.,
Müller Beat,
Tamm Christoph
Publication year - 1973
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19730560834
Subject(s) - chemistry , farnesyl pyrophosphate , pyrophosphate , hydride , stereochemistry , double bond , strain (injury) , terpene , biosynthesis , medicinal chemistry , organic chemistry , enzyme , hydrogen , medicine
In the course of the biosynthesis of verrucarol ( 3 ) from farnesyl pyrophosphate in Myrothecium roridum , strain S 1135, a hydride shift occurs from the central double bond of the precursor to C(2) of the product.