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Oxydative Umsetzungen in der Damascon‐Reihe. 1 Δ g O 2 ‐ und SeO 2 ‐Oxydation von β‐Damascenon
Author(s) -
SchulteElte Karl H.,
Gadola Marcel,
Ohloff Günther
Publication year - 1973
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19730560625
Subject(s) - chemistry , photooxygenation , medicinal chemistry , selenium , peroxide , oxygen , singlet oxygen , organic chemistry
Photooxygenation of β‐damascenone ( 1 ) leads to the 3,6‐ endo ‐peroxide ( 2 ) which has been converted to various oxygenated derivatives in the damascene series. Introduction of oxygen specifically into the 2‐position of β‐damascenone ( 1 ) occurs by selenium dioxide oxidation. A series of reduction products of 2‐oxo‐β‐damascone ( 9 ) is described.