Metallbindungsphänomene: Alkoholat‐Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen | Zendy

Schlosser Manfred | Zendy; Jan Gérald | Zendy; Byrne Edeline | Zendy; Sicher Jiři | Zendy

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Metallbindungsphänomene: Alkoholat‐Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen

Author(s) -

Schlosser Manfred,

Jan Gérald,

Byrne Edeline,

Sicher Jiři

Publication year - 1973

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19730560519

Subject(s) - chemistry , dehydrohalogenation , carbanion , stereochemistry , polarity (international relations) , aggregate (composite) , organic chemistry , catalysis , nanotechnology , biochemistry , materials science , cell

In solvents of low polarity it is neither a monomolecular nor a dissociated alcoholal species which effects dehydrohalogenation of vic ‐dihaloalkanes and vic ‐dihalocycloalkanes but rather a dimeric, trimeric or tetrameric alcoholate aggregate. This behavior has important implications for the stereochemical outcome of such elimination reactions.

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