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Synthese und Eigenschaften einiger neuer Mono(π‐cyclopentadienyl)‐Nickel‐Komplexe
Author(s) -
Harder Viktor,
Werner Helmut
Publication year - 1973
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19730560518
Subject(s) - chemistry , nickelocene , nickel , ionic bonding , ligand (biochemistry) , transition metal , phosphonate , cyclopentadienyl complex , metal , medicinal chemistry , stereochemistry , polymer chemistry , ion , organic chemistry , catalysis , ferrocene , biochemistry , receptor , electrode , electrochemistry
During studies on the mechanism of ligand displacement reactions of nickelocene non‐ionic monocyclopentadienylnickel complexes of the type πC 5 H 5 Ni[P(OP) 3 ]X with X = Cl and P(O) (OR) 2 have been obtained. The new compounds have been characterised by means of their IR., UV., NMR. and Mass spectroscopic data. The phosphonate ligands are bonded with the phosphorus atom to the transition metal.