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Spectre de Resonance Paramagnétique Electronique de la Diphénylthiophosphine cristalline irradiée aux rayons X
Author(s) -
Geoffroy Michel
Publication year - 1973
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19730560511
Subject(s) - chemistry , diphenylphosphine , electron paramagnetic resonance , hyperfine structure , crystallography , sulfide , resonance (particle physics) , nuclear magnetic resonance , physics , atomic physics , phosphine , organic chemistry , catalysis
The electron spin resonance spectra of X‐irradiated diphenylphosphine sulfide monocrystal and powder are reported. The results show that the radical Φ 2 \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {\rm P}\limits^{.} $\end{document} S is mainly produced. The values and directions of the principal components of ḡ and 31 P‐hyperfine tensors are determined.