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Homopolar and Heteropolar Bond Dissociation Energies and Heats of Formation of Radicals and Ions in the Gas Phase II. The relationship between structure and bond dissociation in organic molecules
Author(s) -
Egger Kurt W.,
Cocks Alan T.
Publication year - 1973
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19730560510
Subject(s) - chemistry , bond dissociation energy , dissociation (chemistry) , delocalized electron , homopolar motor , radical , ion , gas phase , substituent , bond energy , computational chemistry , molecule , bond order , bond length , stereochemistry , organic chemistry , physics , quantum mechanics , magnet
The preceeding paper presents a critical tabular compilation of 2‐center homo‐ and heteropolar bond dissociation energies. This paper deals with some empirically derived general aspects of these data, particularly regarding relationships between structure and reactivity, i.e . substituent effects on bond dissociation energies. ‘Extra’ stabilization energies generated in electronically delocalized radicals or ions derived from these experimental data are also presented.