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The Nitrosation of Primary Aliphatic Diazocarbonyl Compounds: Formation of α‐carbonyl nitrile oxides. Preliminary communication
Author(s) -
Dahn Hans,
Favre B.,
Leresche J.P.
Publication year - 1973
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19730560136
Subject(s) - chemistry , nitrile , diazo , primary (astronomy) , nitrosation , ethyl diazoacetate , organic chemistry , aqueous solution , catalysis , cyclopropanation , physics , astronomy
Aqueous nitrosation of primary α‐carbonyl diazo compounds (ethyl diazoacetate, diazoacetone, diazoacetophenones) yields α‐carbonyl nitrile oxides, RCOCNO; their formation is demonstrated by 1,3‐dipolar addition reactions.