Antibiotic X‐5108. II . Structure of goldinono‐1, 4‐lactone‐3, 7‐hemiketal, a degradation product of the antibiotic. Preliminary communication | Zendy

Maehr Hubert | Zendy; Blount John F. | Zendy; Evans Ralph H. | Zendy; Leach Michael | Zendy; Westley John W. | Zendy; Williams Thomas H. | Zendy; Stempel Arthur | Zendy; Büchi George | Zendy

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Antibiotic X‐5108. II . Structure of goldinono‐1, 4‐lactone‐3, 7‐hemiketal, a degradation product of the antibiotic. Preliminary communication

Author(s) -

Maehr Hubert,

Blount John F.,

Evans Ralph H.,

Leach Michael,

Westley John W.,

Williams Thomas H.,

Stempel Arthur,

Büchi George

Publication year - 1972

Publication title -

helvetica chimica acta

Language(s) - German

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19720550837

Subject(s) - chemistry , stereochemistry , antibiotics , lactone , pyran , biochemistry

Antibioticum X‐5108 ist ein Naturprodukt mit neuartiger Struktur. Behandlung des Antibioticums mit Essigsäure führte zu einem kristallinen Abbauprodukt, das als 3( S )‐Äthyl‐3, 3a, 5( S ), 6, 7, 7 a( R )‐hexahydro‐3a( R ), 7( R )‐dihydroxy‐6, 6‐dimethyl‐5‐[1( cis ), 3( trans )‐pentadienyl]‐2 H ‐furo[3, 2‐ b ]pyran‐2‐on ( 5 ) identifiziert wurde.

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