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Etudes sur les composés organométalliques XIV . Réactivité du tétrabenzyltitane (l ère communication)
Author(s) -
Causse Jacques,
Tabacchi Raffaele,
JacotGuillarmod André
Publication year - 1972
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19720550519
Subject(s) - chemistry , benzonitrile , acetone , reactivity (psychology) , benzophenone , medicinal chemistry , propylene oxide , chloride , carbon dioxide , toluene , organic chemistry , medicine , alternative medicine , ethylene oxide , pathology , copolymer , polymer
The reactivity of tetrabenzyltitanium with acetone, benzophenone, butanal, acetyl chloride, butyl acetate, ethyl chloroformate, benzonitrile, propylene oxide, carbon dioxide has been investigated. The results show that tetrabenzyltitanium reacts like benzylmagnesium‐chloride. The socalled ‘anomalous reaction’ is observed. Benzonitrile, propylene oxide and carbon dioxide, on the other hand, do not react.