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Eine neue Amidinsynthese mit Hilfe der Grignard ‐Reaktion. 7. Mitteilung über Grignard ‐Reaktionen [1]
Author(s) -
Marxer A.
Publication year - 1972
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19720550213
Subject(s) - chemistry , benzonitrile , grignard reaction , medicinal chemistry , grignard reagent , yield (engineering) , imide , polymer chemistry , organic chemistry , catalysis , reagent , materials science , metallurgy
In an unusual manner benzonitrile 5 and the substituted benzonitriles 1 , 14 reacted with benzylmagnesiumhalides to yield, besides dibenzyl, the amidines 7 , 13 , 15 , substituted on the imide nitrogen by a 1,2‐diphenyl‐vinyl group. The proposed structures are based on NMR. and mass spectra.
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