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Réactions de substitution dans l'anion tétrachloropalladate(II) avec des diamines. I. Ethylènediamine
Author(s) -
Roulet R.,
Ernst R.
Publication year - 1971
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19710540802
Subject(s) - chemistry , ethylenediamine , medicinal chemistry , inorganic chemistry
The replacement of Cl − by ethylenediamine (en) in PdCl 2− 4has been followed spectrophotometrically at 25°C and μ = 1 (NaClO 4 ); it proceeds in two steps leading to Pd(en)Cl 2 and Pd(en) 2+ 2 , respectively. The observed rate constants are discussed in terms of the mechanism proposed by Reinhardt [1] for the successive ammination reactions of PdCl 2− 4 .
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