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Darstellung von (+)‐ und (−)‐7‐Hydroxy‐dihydrocitronellal aus (+)‐Pulegon. Ein Beitrag zur Kenntnis olfaktorischer Eigenschaften von Enantiomeren
Author(s) -
Skorianetz W.,
Giger H.,
Ohloff G.
Publication year - 1971
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19710540707
Subject(s) - chemistry , enantiomer , pulegone , stereochemistry , chromatography , essential oil
The enantiomers of 7‐hydroxy‐dihydrocitronellal have been prepared stereo‐specifically from (+)‐pulegone by a sequence of analogous reactions. The olfactory properties of the final products and of the intermediates have been investigated. In most cases they exhibit remarkable qualitative and quantitative differences in odour.