Mass Spectrometry and Organic Analysis, part 14.  The photolysis and mass spectra of medium and large ring ketones from C 9  to C 16 | Zendy

SchulteElte K. H. | Zendy; Willhalm B. | Zendy; Thomas A. F. | Zendy; Stoll M. | Zendy; Ohloff G. | Zendy

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Mass Spectrometry and Organic Analysis, part 14. The photolysis and mass spectra of medium and large ring ketones from C 9 to C 16

Author(s) -

SchulteElte K. H.,

Willhalm B.,

Thomas A. F.,

Stoll M.,

Ohloff G.

Publication year - 1971

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19710540703

Subject(s) - chemistry , mass spectrum , mass spectrometry , photodissociation , hydrogen atom , ring (chemistry) , ketone , spectral line , photochemistry , hydrogen , medicinal chemistry , analytical chemistry (journal) , organic chemistry , group (periodic table) , chromatography , physics , astronomy

The photolysis of cyclic ketones from C 9 to C 16 has been carried out, and formation of cyclobutanols observed in only C 11 to C 16 . Although in the mass spectrometer cyclobutanols are not formed, an initial transfer of a γ‐hydrogen atom to the carbonyl group is shown to occur in the mass spectra of all cyclic ketones higher than C 10 .

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