Contribution à l'étude du système quaternaire KClRbClCsClH 2 O: II. L'isotherme de 25°C | Zendy

Merbach A. | Zendy; Gonella J. | Zendy

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Contribution à l'étude du système quaternaire KClRbClCsClH 2 O: II. L'isotherme de 25°C

Author(s) -

Merbach A.,

Gonella J.

Publication year - 1971

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19710540519

Subject(s) - chemistry , miscibility , solubility , spinodal decomposition , binary system , phase diagram , binary number , solid solution , crystallography , analytical chemistry (journal) , thermodynamics , chromatography , organic chemistry , phase (matter) , polymer , physics , arithmetic , mathematics

The experimental study at 25°C of the system KClRbClCsClH 2 O has shown the existence of a new type of quaternary system with formation of mixed crystals. — The solubility diagram is characterized by the presence of one univariant line and one binary miscibility gap. Two types of solid solutions are present: ( K, Rb , Cs) Cl and (K, Rb, Cs ) Cl; the incorporation in the latter is small.

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