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Contribution à l'étude du système quaternaire KClRbClCsClH 2 O: II. L'isotherme de 25°C
Author(s) -
Merbach A.,
Gonella J.
Publication year - 1971
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19710540519
Subject(s) - chemistry , miscibility , solubility , spinodal decomposition , binary system , phase diagram , binary number , solid solution , crystallography , analytical chemistry (journal) , thermodynamics , chromatography , organic chemistry , phase (matter) , polymer , physics , arithmetic , mathematics
Abstract The experimental study at 25°C of the system KClRbClCsClH 2 O has shown the existence of a new type of quaternary system with formation of mixed crystals. — The solubility diagram is characterized by the presence of one univariant line and one binary miscibility gap. Two types of solid solutions are present: ( K, Rb , Cs) Cl and (K, Rb, Cs ) Cl; the incorporation in the latter is small.