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Methoxokomplexe drei‐, vier‐ und fünfwertiger Zentralatome
Author(s) -
Gut R.,
Schmid Eduard,
Serrallach Jorge
Publication year - 1971
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19710540219
Subject(s) - chemistry , stoichiometry , titration , inorganic chemistry , crystallography , stereochemistry , nuclear chemistry , medicinal chemistry
The complex formation with CH 3 O − of As III , Sb III , Ge IV , Nb IV , Se IV , Te IV , Ti IV , Sn IV and Mo V has been investigated in absolute methanolic solutions containing (CH 3 ) 4 NCl, LiCl, or Lithiumtosylate (μ = 1; 20.0°) by means of pH‐titrations. The relations between the stoichiometry of the reactions and the shape of the buffer regions, as well as the concentration‐dependance of these buffer regions are discussed.