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Ligandenverdrängungsreaktionen von Kobalt‐dicyclopentadienyl mit tertiären Phosphiten – Darstellung und Eigenschaften der Komplexe C 5 H 5 Co[P(OR) 3 ] 2
Author(s) -
Harder V.,
Müller J.,
Werner H.
Publication year - 1971
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19710540102
Subject(s) - chemistry , mass spectrum , crystallography , medicinal chemistry , mass spectrometry , chromatography
The reaction of Co(C 5 H 5 ) 2 with tertiary phosphites mainly gives the half‐sandwich type compounds C 5 H 5 Co[P(OR) 3 ] 2 (R = CH 3 , C 2 H 5 , C 6 H 5 ), which are characterised by means of their IR., UV., and NMR. spectroscopic data. The mass spectra of the new compounds are discussed.