Synthèse électrochimique du cycle époxydique. Communication préliminaire | Zendy

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Synthèse électrochimique du cycle époxydique. Communication préliminaire

Author(s) -

Gerdil Raymond

Publication year - 1970

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19700530820

Subject(s) - chemistry , polarography , intramolecular force , electrolysis , cathode , medicinal chemistry , mercury (programming language) , cleavage (geology) , stereochemistry , electrode , inorganic chemistry , geotechnical engineering , fracture (geology) , computer science , engineering , electrolyte , programming language

The polarographic behaviour of ditosyloxy alkanes TsO(CH 2 ) n OTs in aprotic medium suggests that intramolecular cyclisation takes place after reductive cleavage of a single SO 2 O bond at the dropping electrode. This hypothesis was verified by controlled potential electrolysis of the lower homologues at a mercury cathode. High yields of epoxy compounds are obtained by this method.

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