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Oxymercuration. Substituted 9‐oxabicyclo[4.2.1]‐ and 9‐ oxabicyclo[3.3.1]nonanes
Author(s) -
Ganter C.,
Wicker K.,
Zwahlen W.,
SchaffnerSabba K.
Publication year - 1970
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19700530709
Subject(s) - nonane , chemistry , iodine , iodide , medicinal chemistry , stereochemistry , organic chemistry
Oxymercuration of cis , cis ‐1, 5‐cyclooctadiene ( 1 ), followed by treatment with potassium iodide and subsequent reaction with iodine, leads to six isomeric diiodides which represent the three possible stereoisomers 2 , 3 , and 4 of 2, 5‐diiodo‐9‐oxabicyclo[4.2.1]nonane as well as 5 , 6 , and 7 of 2, 6‐diiodo‐9‐oxabicyclo[3.3.1]nonane. The isolation, structure determination and some reactions of these diiodo compounds 2 – 7 are described.
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