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Flexional Effects in Bridged Bicyclic Molecules Progressive Flattening of Chair Cyclohexane
Author(s) -
Jefford C. W.,
Baretta A.,
Fournier J.,
Waegell B.
Publication year - 1970
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19700530534
Subject(s) - chemistry , flattening , cyclohexane , bicyclic molecule , cyclohexanol , molecule , coupling constant , computational chemistry , stereochemistry , organic chemistry , composite material , quantum mechanics , catalysis , physics , materials science
Measures of the progressive flattening of the chair conformation in a series of constrained cyclohexanols are obtained and compared by proton NMR. coupling constants and by molecular mechanics.