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Photochemische Darstellung von Hexaalkylborazol‐und Aromaten‐chromtricarbonylen
Author(s) -
Deckelmann K.,
Werner H.
Publication year - 1970
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19700530118
Subject(s) - chemistry , medicinal chemistry , ligand (biochemistry) , stereochemistry , receptor , biochemistry
The half‐sandwich type complexes LCr(CO) 3 (L=(C 2 H 5 ) 3 B 3 N 3 (CH 3 ) 3 , (CH 3 ) 3 B 3 N 3 (C 2 H 5 ) 3 , C 6 H 6 , sym ‐C 6 H 3 (CH 3 ) 3 ) have been prepared by photochemical reaction of Cr(CO) 6 with the appropriate ligand L at highly reduced pressure. This new method is of particular advantage for the synthesis of the hexaalkylborazole complexes.