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Cyclization of the Enol Esters of o ‐Acyloxyphenyl Alkyl Ketones, IV. A kinetic study of the steps of the K OSTANECKI ‐R OBINSON reaction
Author(s) -
Széll T.,
Kovács K.,
Zarándy M. S.,
Erdőhelyi Á.
Publication year - 1969
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19690520844
Subject(s) - chemistry , propiophenone , enol , reaction rate constant , alkyl , medicinal chemistry , stereochemistry , reaction mechanism , kinetics , ketone , organic chemistry , catalysis , physics , quantum mechanics
In a study of the K OSTANECKI ‐R OBINSON reaction of 2,4‐diacetoxy‐6‐hydroxy‐propiophenone the rate constants and the order of each step have been approximately determined and compared. Mechanism for the reaction is suggested.