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Tetrafluordiazabuten‐Derivate aus Chlorcyan
Author(s) -
Alt K. O.,
Weis C. D.
Publication year - 1969
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19690520332
Subject(s) - chemistry , yield (engineering) , medicinal chemistry , organic chemistry , stereochemistry , metallurgy , materials science
Cyanogenchloride reacts in liquid hydrogenfluoride with fluorides of some aliphatic hydrocarbons to yield derivatives of 2,4,4,4‐tetrafluoro‐1,3‐diazabut‐2‐ene. The mechanism of its formation is explained in terms of an intermediate fluorinated linear dimerization product of cyanogenchloride. Reactions of the N‐trifluoromethylgroup are reported.